Physico-chemical and catalytic properties of polymer-protected and hydrogel-immobilized gold, silver and palladium nanoparticles
Keywords:
Gold, silver, palladium, nanoparticles, hydrophilic polymers, hydrogel, immobilizationAbstract
Gold (AuNPs), silver (AgNPs) and palladium (PdNPs) nanoparticles stabilized by various hydrophilic polymers are considered. Embedding of polymer-protected AuNPs, AgNPs and PdNPs within hydrogel matrix restricts the diffusion of nanoparticles both inside of and outside of gel matrix. Catalytic properties of metal nanoparticles supported onto either metal oxides or immobilized within hydrogel matrix have been studied in model reaction – decomposition of hydrogen peroxide. The influence of catalyst amount (mcat), concentration of substrate (H2O2) and temperature (T) was studied in order to find the optimal conditions of H2O2 decomposition. Examples of hydrogel-based catalytic system acting by “on-off” mechanism are demonstrated. The catalytic activity of gel-immobilized metal nanoparticles is proved to be much lower than deposited on the metal oxides due to lesser accessibility of active centers in hydrogel matrix to substrate molecules.References
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6 Ram, S., Agrawal, L.,Mishra, A.,Roy, S.K. Synthesis and optical properties of surface stabilized gold nanoparticles with poly(N-vinylpyrrolidone) Polymer molecules of a nanofluid // Advanced Science Letters –2011. – Vol. 4(11-12). – P. 3431-3438.
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9 Dorris A., Rucareanu S., Reven L., Barrett C.J., Bruce L.R. Preparation and characterization of polyelectrolyte-coated gold nanoparticles // Langmuir – 2008. – Vol.4. – P. 2532-2538.
10 Sardar R., Bjorge N.S., Shumaker-Parry J.S. pH-controlled assemblies of polymeric amine-stabilized gold nanoparticles // Macromolecules – 2008. – Vol. 41(12). – P. 4347-4352.
11 Chen H., Lentz D.M., Hedden R.C. Solution templating of Au and Ag nanoparticles by linear poly[2-(diethylamino)ethyl methacrylate] // Journal of Nanoparticle Research – 2012. – Vol. 14(2) Article number 690.
12 Note C., Koetz J., Wattebled L., Laschewsky A. Effect of a new hydrophobically modified polyampholyte on the formation of inverse microemulsions and the preparation of gold nanoparticles // Journal of Colloid and Interface Science - 2007. – Vol.308. – P. 162-169.
13 Li S., Wu Y., Wang J., Zhang Q., Kou Y., Zhang S. Double-responsive polyampholyte as a nanoparticle stabilizer: Application to reversible dispersion of gold nanoparticles // Journal of Materials Chemistry - 2010. – Vol. 20(21). – P. 4379-4384.
14 Mahltig B., Cheval N., Gohy J.-F., Fahmi A. Preparation of gold nanoparticles under presence of the diblock polyampholyte PMAA-b-PDMAEMA // Journal of Polymer Research – 2010. – Vol.17(4). – P. 579-588.
15 Bekturov E.A., Kudaibergenov S.E., Iskakov R.M., Zharmagambetova A.K., Ibraeva Zh.E., Shmakov S. Polymer-Protected Nanoparticles of Metals. (in Russian), Almaty, 2010.
16 Ibrayeva Zh.E., Kudaibergenov S.E., Bekturov E.A. Stabilization of Metal Nanoparticles by Hydrophilic Polymers. (in Russian), LAP Lambert Academic Publishing, Saarbrucken, Germany, 367 p.
17 Ram S., Agrawal L., Mishra A., Roy S.K. Synthesis and optical properties of surface stabilized gold nanoparticles with poly(N-vinylpyrrolidone) Polymer molecules of a nanofluid // Advanced Science Letters – 2011. – Vol. 4(11-12). – P. 3431-3438.
18 Hoppe C. E., Massimo L., Iva´n Pardin˜as-Blanco, M. Arturo Lo´pez-Quintela. One-Step Synthesis of Gold and Silver Hydrosols Using Poly(N-vinyl-2-pyrrolidone) as a Reducing Agent // Langmuir – 2006. - Vol. 22. – P. 7027-7034.
19 Haruta M. Novel catalysis of gold deposited on metal oxides // Catalysis Surveys from Japan – 1997. – Vol.1. – P. 61-73.
20 Haruta M., Daté M. Advances in the catalysis of Au nanoparticles (Review) // Applied Catalysis A: General - 2001. – Vol. 222(1-2). – P. 427-437.
21 Shiju N.R., Guliants, V.V. Recent developments in catalysis using nanostructured materials (Review ) // Applied Catalysis A: General – 2009. – Vol. 356. – P. 1-17.
22 Zhang Y., Cattrall R.W., McKelvie I.D., Kolev S.D. Gold, an alternative to platinum group metals in automobile catalytic converters (Review) // Gold Bulletin - 2011. – Vol. 44 (3). – P. 145-153.
23 Dolya N., Rojas O., Kosmella S., Tiersch B., Koetz J., Kudaibergenov S. “One-Pot” in situ Formation of Gold Nanoparticles within Poly(acrylamide) Hydrogels // Macromol. Chem. Phys.- 2013. - Vol.214. - P.114-1121.
24 Pardo-Yissar V., Gabai R., Shipway A. N., Bourenko T., Willner I. Gold Nanoparticle/Hydrogel Composites with Solvent-Switchable Electronic Properties // Adv. Mater.- 2001. – Vol.13. – P.1320-1323.
25 Sheeney-Hai-Ichia L., Sharabi G., Willner I. Control of the Electronic Properties of Thermosensitive Poly(N-isopropylacrylamide) and Au-Nano-particle/Poly(N-isopropylacrylamide) Composite Hydrogels upon Phase Transition // Adv. Funct. Mater. – 2002. - Vol. 12. – P.27-32.
26 Weissman J. M., Sunkara H. B., Tse A. S., Asher S. A. Thermally Switchable Periodicities from Novel Mesocopically Ordered Materials // Science – 1996. – Vol. 274. – P. 959-960.
27 Holtz J. H. and Asher S. A. Polymerized Colloidal Crystal Hydrogel Films as Intelligent Chemical Sensing Materials // Nature –1997. - Vol. 389. – P.829-832.
28 Lee Y.-J., Braun P. V. Tunable Inverse Opal Hydrogel pH Sensors // Adv. Mater. - 2003. – Vol.15. – P. 563-566.
29 Sershen S. R., Westcott S. L., Halas N. J., and West J. L. Temperature-sensitive polymer–nanoshell composites for photothermally modulated drug delivery // J. Biomed .Mater. Res. – 2000. – Vol.51. – P. 293-298.
30 Sershen S. R., Westcott S. L., West J. L., Halas N. J. An Opto-Mechanical Nanoshell-Polymer Composite// Appl. Phys. B. – 2001. – Vol.73. – P. 379-381.
31 Wang C., Flynn N. T., Langer R. Controlled structure and properties of thermoresponsive nanoparticle–hydrogel composites // Adv. Mater. – 2004. – Vol.16. – P. 1074-1079.
32 S. E. Kudaibergenov, Zh. E. Ibraeva, N. A. Dolya, et al. Semi-Interpenetrating Hydrogels of Polyelectrolytes, Polymer-Metal Complexes and Polymer-Protected Palladium Nanoparticles // Macromolecular Symposia – 2008. – Vol.274. – P.11 – 21.
33 Dolya N.A. Physico-chemical and catalytic properties of polymer-protected and gel-immobilized metals nanoparticles. PhD Thesis.Almaty – 2009.
34 Zhang J., Zhao B., Meng L., Wu H., Wang X., and Li Ch. Controlled synthesis of gold nanospheres and single crystals in hydrogel // J. Nanopart.Res. – 2007. – Vol.9. – P. 1167-1171.
35 Kim J.-H., Lee T. R. Hydrogel-Templated Growth of Large Gold Nanoparticles: Synthesis of Thermally Responsive Hydrogel-Nanoparticle Composites // Langmuir – 2007. – Vol.23. – P. 6504-6509.
36 Hagiwara H., Shimizu Y., Hoshi T., Suzuki T., Ando M., Ohkubo K., and Yokoyama C. Heterogeneous Heck reaction catalyzed by Pd/C in ionic liquid // Tetrahedron Lett. – 2001. – Vol.42. – P. 4349 - 4351.
37 Kohler K., Heidenreich R.G., Krauter J.G.E., Pietsch M. Highly active palladium/activated carbon catalysts for heck reactions: Correlation of activity, catalyst properties, and Pd leaching // Chem. – Eur. J. – 2001. – Vol.8. – P. 622–631.
38 Phan N.T.S., Brown D.H., Styring P. A polymer-supported salen-type palladium complex as a catalyst for the Suzuki-Miyaura cross-coupling reaction // Tetrahedron Letters – 2004. – Vol. 45(42). – P. 7915-7919.
39 Lu F., Ruiz J., Astruc D. Palladium-dodecanethiolate nanoparticles as stable and recyclable catalysts for the Suzuki-Miyaura reaction of aryl halides under ambient conditions // Tetrahedron Letters – 2004. – Vol. 45(51). – P. 9443-9445.
40 Leadbeater N.E., Marco M. Ligand-free palladium catalysis of the Suzuki reaction in water using microwave heating // Organic Letters – 2002. – Vol. 4(17). – P. 2973-2976.
41 Sivudu K. S., Reddy N. M., Prasad M. N., et al. Highly efficient and reusable hydrogel-supported nano-palladium catalyst: Evaluation for Suzuki-Miyaura reaction in water // Journal of Molecular Catalysis A: Chemical. – 2008. – Vol. 295(1–2). – P.10-17.
42 Wu H., Wang L., Zhang,J., Shen Z., and Zhao J. Catalytic oxidation of benzene, toluene and p-xylene over colloidal gold supported on zinc oxide catalyst // Catalysis Communications - 2011. – Vol. 12(10). – P.859-865.
43 Lü G., Ji D., Qian G., Qi Y., Wang X., and Suo, J. Gold nanoparticles in mesoporous materials showing catalytic selective oxidation cyclohexane using oxygen // Applied Catalysis A: General – 2005. – Vol. 280(2). – P.175-180.
44 Hu N., Yin J.-Y., Tang Q., Chen Y. Comparative study of amphiphilic hyperbranched and linear polymer stabilized organo-soluble gold nanoparticles as efficient recyclable catalysts in the biphasic reduction of 4-nitrophenol // Journal of Polymer Science, Part A: Polymer Chemistry - 2011. – Vol. 49(17). – P.3826-3834.
45 Kudaibergenov S. E., Tatykhanova G.S., Baigaziyeva E. Preparation, Characterization and Catalytic Activity of Gold Nanoparticles Stabilized by Hydrophilic Polymers. Proceedings of the International Conference “Nanomaterials: Applications and Properties”, NAP-2012, Alushta, Crimea, Ukraine, September 16-22. - 2012. 1(1): 01PCN-42.
46 Yesmurzayeva N., Selenova B., Kudaibergenov S. Preparation and Catalytic Activity of Gold Nanoparticles Stabilized by Poly(N-Vinylpyrrolidone) and Deposited onto Aluminum Oxide // Journal of American Nanomaterials - 2013. – Vol. 1(1). – P.1-4.
47 Kudaibergenov S., Yesmurzayeva N., Baygazieva E. Synthesis, characterization and catalytic activity of gold nanoparticles protected by poly(N-vinylpyrrolidone). Austrian-Slovenian Polymer Meeting ASPM-2013, Bled, Slovenia, 3-5 April. 2013. – P.216-217.
48 Kudaibergenov S.E., Baigaziyeva E.K., Yesmurzayeva N.N., Nurakhmetova Zh.A, Selenova B.S. Synthesis, Characterization and Catalytic Property of Polymer Protected Gold and Silver Nanoparticles //Proceedings of the International Conference “Nanomaterials: Applications and Properties” - 2013. – Vol. 2 (2): 02PCN03. – P. 4.
49 Kidambi S., Dai J.H., Li J., Bruening M.L. Selective hydrogenation by Pd nanoparticles embedded in polyelectrolyte multilayers //J Am Chem Soc. - 2004. – Vol. 126. – P. 2658–2659.
50 Metin O., Sahin S., Ozkar S. Water-soluble poly(4-styrenesulfonic acid-co-maleic acid) stabilized ruthenium(0) and palladium(0) nanoclusters as highly active catalysts in hydrogen generation from the hydrolysis of ammonia-borane // Int J Hydrogen Energy. - 2009. – Vol. 34. – P. 6304–6313.
51 Jiang H.Q., Manolache S., Wong A.C.L, Denes F.S. Plasma-enhanced deposition of silver nanoparticles onto polymer and metal surfaces for the generation of antimicrobial characteristics // J Appl Polym Sci. - 2004. – Vol. 93. – P.1411–1422
52 Wunder S., Lu Y., Albrecht M., Ballauff M.. Catalytic activity of faceted gold nanoparticles studied by a model reaction: evidence for substrate-induced surface restructuring. ACS Catal. – 2011. – Vol. 1. – P. 908–916.
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Published
2013-12-20
How to Cite
Kudaibergenov, Sarkyt E., and Gulnur S. Tatykhanova. 2013. “Physico-Chemical and Catalytic Properties of Polymer-Protected and Hydrogel-Immobilized Gold, Silver and Palladium Nanoparticles”. International Journal of Biology and Chemistry 6 (2):40-49. https://ijbch.kaznu.kz/index.php/kaznu/article/view/98.
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