Oxidation of Cyclohexane Mediated with Gel-Immobilized Gold Nanoparticles
DOI:
https://doi.org/10.26577/2218-7979-2015-8-1-61-66Keywords:
gold nanoparticles, hydrogels, hydrophilic polymers, stabilization, catalysisAbstract
This paper reports the study of hydrogen peroxide decomposition and oxidation of cyclohexane catalyzed by polymerprotected gold nanoparticles (AuNPs) immobilized within polyacrylamide hydrogel. The stabilization of AuNPs was achieved using nonionic, anionic and cationic polymers. embedding of AuNPs stabilized with various polymers into polyacrylamide hydrogels was carried out using threeways: «in situ» polymerization, sorption and boronhydride methods. Size, shape and morphology of AuNPs were characterized by various physicochemical methods. Application aspects of polymer-protected AuNPs in catalysis are outlined.References
1 Enrica Caló, Vitaliy V. Khutoryanskiy, Biomedical applications of hydrogels: a review of patents and commercial products, European Polymer Journal.
2 K. Pal, A. K. Banthia, D. K.Majumdar, Polymeric Hydrogels: Characterization and Biomedical Applications – a mini review, Designed monomers and polymers 12 (2009). – P. 197-220.
3 Bindu Sri. M, Ashok. V and Arkendu Chatterjee. Review on Hydrogels as Drug Delivery in thePharmaceutical Field, Vol. 1 (2) Apr – Jun 2012 Pages 642-661.
4 Enas M. Ahmed. Hydrogel: Preparation, characterization, and applications: a review. Journal of Advanced Research, Volume 6, Issue 2, March 2015, Pages 105–121.
5 Praveen Thoniyot, Mein Jin Tan, Anis Abdul Karim, David James Young, Xian Jun Loh. Nanoparticle–Hydrogel Composites: Concept, Design, and
Applications of These Promising, Multi-Functional Materials, Adv. Sci. 2015.
6 V. Pardo-Yissar, R. Gabai, A.N. Shipway, T. Bourenko, I. Willner, Adv. Mater. 2001, 13, 1320.
7 C. Wang, N.T. Flynn, R. Langer, Adv. Mater. 2004, 16, 1074.
8 N.S. Satarkar, D. Biswal, J.Z. Hilt, Soft Matter 2010, 6, 2364.
9 S. R. Sershen, S. L. Westcott, N. J. Halas, J. L. West, Appl. Phys. Lett. 2002, 80, 4609.
10 N. Ravi, H. A. Aliyar, P. D. Hamilton, Macromol. Symp. 2005, 227, 191.
11 Q.-B. Wei, F. Fu, Y.-Q. Zhang, L. Tang, J. Polym. Res. 2014, 21, 1.
12 K.A. Juby, C. Dwivedi, M. Kumar, S. Kota, H.S. Misra, P. N. Bajaj, Carbohydr. Polym. 2012, 89, 906.
13 R.-C. Luo, Z.H. Lim, W. Li, P. Shi, C.-H. Chen, Chem. Commun. 2014, 50, 7052.
2 K. Pal, A. K. Banthia, D. K.Majumdar, Polymeric Hydrogels: Characterization and Biomedical Applications – a mini review, Designed monomers and polymers 12 (2009). – P. 197-220.
3 Bindu Sri. M, Ashok. V and Arkendu Chatterjee. Review on Hydrogels as Drug Delivery in thePharmaceutical Field, Vol. 1 (2) Apr – Jun 2012 Pages 642-661.
4 Enas M. Ahmed. Hydrogel: Preparation, characterization, and applications: a review. Journal of Advanced Research, Volume 6, Issue 2, March 2015, Pages 105–121.
5 Praveen Thoniyot, Mein Jin Tan, Anis Abdul Karim, David James Young, Xian Jun Loh. Nanoparticle–Hydrogel Composites: Concept, Design, and
Applications of These Promising, Multi-Functional Materials, Adv. Sci. 2015.
6 V. Pardo-Yissar, R. Gabai, A.N. Shipway, T. Bourenko, I. Willner, Adv. Mater. 2001, 13, 1320.
7 C. Wang, N.T. Flynn, R. Langer, Adv. Mater. 2004, 16, 1074.
8 N.S. Satarkar, D. Biswal, J.Z. Hilt, Soft Matter 2010, 6, 2364.
9 S. R. Sershen, S. L. Westcott, N. J. Halas, J. L. West, Appl. Phys. Lett. 2002, 80, 4609.
10 N. Ravi, H. A. Aliyar, P. D. Hamilton, Macromol. Symp. 2005, 227, 191.
11 Q.-B. Wei, F. Fu, Y.-Q. Zhang, L. Tang, J. Polym. Res. 2014, 21, 1.
12 K.A. Juby, C. Dwivedi, M. Kumar, S. Kota, H.S. Misra, P. N. Bajaj, Carbohydr. Polym. 2012, 89, 906.
13 R.-C. Luo, Z.H. Lim, W. Li, P. Shi, C.-H. Chen, Chem. Commun. 2014, 50, 7052.
Downloads
How to Cite
Nurgaziyeva, E. K., G. S. Tatykhanova, G. A. Mun, V. V. Khutoryanskiy, and S. E. Kudaibergenov. 2015. “Oxidation of Cyclohexane Mediated With Gel-Immobilized Gold Nanoparticles”. International Journal of Biology and Chemistry 8 (1):61-66. https://doi.org/10.26577/2218-7979-2015-8-1-61-66.
Issue
Section
Chemistry
License
ааа
