Development of polyurethane dispersion based on aromatic isocyanat: influence of NCO/OH ratio on physico-mechanical properties of PUD
DOI:
https://doi.org/10.26577/2218-7979-2016-9-1-73-78Keywords:
polyurethanes, NCO/OH ratio, mechanical properties, physical properties, TDIAbstract
Aqueous polyurethane dispersions (PUDs) were prepared by the prepolymer mixing technique solventfree using aromatic isocyanat[toluene diisocyanate (TDI)], poly(oxytetramethylene) glycol (PTMG), dimethylol propionic acid (DMPA). The properties of both the dispersion’s and casting polymer films were characterized byparticle size analyzer, viscosity and tensile tester. IR spectroscopy was used to check the end of polymerization reaction and characterization of polymer. The effect of NCO/OH molar ratio on the physico-mechanical properties of the polyurethanes was studied. Results showed that tensile strength, contact angle and average particle size increase with increase of NCO/OH molar ratios. Elongation at break and viscosity decrease with increase of NCO/OH molar ratios.References
1. Saetung, A., Rungvichaniwat, A., Campistron, I., Klinpituksa, P., Laguerre, A., Phinyocheep, P., Pilard, J.F. J. Appl. Polym. Sci., 2010, 117, 1279-1289.
2. Heijkants, R.G.J.C., Calck, R.V., Tienen, T.G., Groot, J.H., Buma, P., Pennings, A.J., Veth, R.P.H., Schouten, A.J. Biomaterials, 2005, 26, 4219-4228.
3. Negim, S.M.; Bahruddin S.; Mahyuddin R.;Idiris, M. S. J. Applied Polymer Science, 2011, 121, 8-13.
4. Sardon H., Irusta L., Fernández-Berridi M.J., Luna J., Lansalot M., Bourgeat-Lami E.Journal of Applied Polymer Science, 2011, 120(4), 2054-2062.
5. Najafi F. ,Manouchehri F. , and Shaabanzadeh M. Journal of Chemical Health Risks, 2011, 1(2): 23-26.
6. Xia Y., Larock R.C., Green Chem., 2010, 12,1893.
7. Pfister D.P., Xia Y., Larock R.C. ChemSus-Chem, 2011, 4, 703.
8. Manvi G.N., Jagtap R.N. J. Disper. Sci. Technol., 2010, 31, 1376.
9. Howarth G.A., Surf. Coat. Int. Pt. B-Coat. Trans., 2003, 86, 111.
10. Pan H., Chen D. Text. Res. J., 2009, 79, 687.
11. Meng Q. B., Lee S.-I., Nah C., Lee Y.-S. Prog. Org. Coat., 2009, 66, 382.
12. Orgilés-Calpena E., Arán-Aís F., Torró-Palau A.M., Orgilés-Barceló C., Martín-Martínez J. M. Int. J. Adhes. Adhes., 2009, 29, 774.
13. Vanessa Durrieu,Alessandro Gandini, Mohamed Naceur Belgacem, Anne Blayo, Gilles Eisele, Jean-Luc Putaux. Journal of Applied Polymer Science, 2004, 94, 700–710.
14. Negim, E.S.M.,Khatib J.M., Shaikhutdinov E.M., YeligbayevaG.Zh., Abulgazievna A.S., Nakan U. International symposium (modern chelenges of higher education and science in the field of chemistry), Almaty, Kazakhstan, May, 30-31, 2013, ISBN 978-601-04-0008-5, p. 21-24.
15. El-SayedNegim, MahyuddinRamli, BahruddinSaad, LyazzatBekbayeva Muhammad IdirisSaleh. Preparation and characterization of water dispersion polyurethane.J. World Applied Sciences, 2011, 12(8), 1145- 1150.
16. El-Sayed Negim, Lyazzat Bekbayeva, Grigority A. Mun, Zhalyrkasyn A. Abilov, Muhammad IdirisSaleh. World Applied Science Journal, 2011, 14(13), 402-407.
17. Piotr K., Pitera B.P. EurPolym J., 2001, 37,251.
18. Tharanikkarasu, K., Kim B.K. J ApplPolym Sci., 1999, 73, 2993.
19. Hourston D.J., Williams G.D., Satguru R., Padget J.C., Pears D. J ApplPolym Sci., 1999, 74, 556.
20. Wen T.C., Wang Y.J., Cheng T.T., Yang C.H. Polymer, 1999, 40, 3979.
21. Zhang S., Cheng L., Hu J. J ApplPolym Sci., 2003, 90, 257.
22. Madbouly S.A., Otaigbe J.U., Nanda A.K., Wicks D.A. Macromolecules, 2005, 38, 4014.
23. Negim E.S.M., Khatib J.M., Faizova E., Shilibekov S., Mussylmanbek S. Middle-Eat Journal of Scientific Research, 16(7): 890-895, 2013.
24. Syrmanova K., Negim E., Kaldybekoekova J., Tuleuov A.M. Oriental Journal of Chemistry. 32(1): 1-7, 2016.
2. Heijkants, R.G.J.C., Calck, R.V., Tienen, T.G., Groot, J.H., Buma, P., Pennings, A.J., Veth, R.P.H., Schouten, A.J. Biomaterials, 2005, 26, 4219-4228.
3. Negim, S.M.; Bahruddin S.; Mahyuddin R.;Idiris, M. S. J. Applied Polymer Science, 2011, 121, 8-13.
4. Sardon H., Irusta L., Fernández-Berridi M.J., Luna J., Lansalot M., Bourgeat-Lami E.Journal of Applied Polymer Science, 2011, 120(4), 2054-2062.
5. Najafi F. ,Manouchehri F. , and Shaabanzadeh M. Journal of Chemical Health Risks, 2011, 1(2): 23-26.
6. Xia Y., Larock R.C., Green Chem., 2010, 12,1893.
7. Pfister D.P., Xia Y., Larock R.C. ChemSus-Chem, 2011, 4, 703.
8. Manvi G.N., Jagtap R.N. J. Disper. Sci. Technol., 2010, 31, 1376.
9. Howarth G.A., Surf. Coat. Int. Pt. B-Coat. Trans., 2003, 86, 111.
10. Pan H., Chen D. Text. Res. J., 2009, 79, 687.
11. Meng Q. B., Lee S.-I., Nah C., Lee Y.-S. Prog. Org. Coat., 2009, 66, 382.
12. Orgilés-Calpena E., Arán-Aís F., Torró-Palau A.M., Orgilés-Barceló C., Martín-Martínez J. M. Int. J. Adhes. Adhes., 2009, 29, 774.
13. Vanessa Durrieu,Alessandro Gandini, Mohamed Naceur Belgacem, Anne Blayo, Gilles Eisele, Jean-Luc Putaux. Journal of Applied Polymer Science, 2004, 94, 700–710.
14. Negim, E.S.M.,Khatib J.M., Shaikhutdinov E.M., YeligbayevaG.Zh., Abulgazievna A.S., Nakan U. International symposium (modern chelenges of higher education and science in the field of chemistry), Almaty, Kazakhstan, May, 30-31, 2013, ISBN 978-601-04-0008-5, p. 21-24.
15. El-SayedNegim, MahyuddinRamli, BahruddinSaad, LyazzatBekbayeva Muhammad IdirisSaleh. Preparation and characterization of water dispersion polyurethane.J. World Applied Sciences, 2011, 12(8), 1145- 1150.
16. El-Sayed Negim, Lyazzat Bekbayeva, Grigority A. Mun, Zhalyrkasyn A. Abilov, Muhammad IdirisSaleh. World Applied Science Journal, 2011, 14(13), 402-407.
17. Piotr K., Pitera B.P. EurPolym J., 2001, 37,251.
18. Tharanikkarasu, K., Kim B.K. J ApplPolym Sci., 1999, 73, 2993.
19. Hourston D.J., Williams G.D., Satguru R., Padget J.C., Pears D. J ApplPolym Sci., 1999, 74, 556.
20. Wen T.C., Wang Y.J., Cheng T.T., Yang C.H. Polymer, 1999, 40, 3979.
21. Zhang S., Cheng L., Hu J. J ApplPolym Sci., 2003, 90, 257.
22. Madbouly S.A., Otaigbe J.U., Nanda A.K., Wicks D.A. Macromolecules, 2005, 38, 4014.
23. Negim E.S.M., Khatib J.M., Faizova E., Shilibekov S., Mussylmanbek S. Middle-Eat Journal of Scientific Research, 16(7): 890-895, 2013.
24. Syrmanova K., Negim E., Kaldybekoekova J., Tuleuov A.M. Oriental Journal of Chemistry. 32(1): 1-7, 2016.
Downloads
How to Cite
Negim, E. S., T. Ketegenov, A. Narimanov, M. Zhangaliyev, H. Rafikova, G. S. Irmukhametova, R. Iskakov, and G. A. Mun. 2016. “Development of Polyurethane Dispersion Based on Aromatic Isocyanat: Influence of NCO/OH Ratio on Physico-Mechanical Properties of PUD”. International Journal of Biology and Chemistry 9 (1):73-78. https://doi.org/10.26577/2218-7979-2016-9-1-73-78.
Issue
Section
Chemistry
License
ааа
