Water soluble copolymers of acrylamide with methylacrylate in reactions of complex formation with polyacrylic acid

  • Zh. K. Zhatkanbayeva Faculty of Chemistry and Chemical Technology, al-Farabi Kazakh National University
  • M. R. Yermagambetova Faculty of Chemistry and Chemical Technology, al-Farabi Kazakh National University
  • A. Amirova Faculty of Chemistry and Chemical Technology, al-Farabi Kazakh National University
  • G. A. Mun Faculty of Chemistry and Chemical Technology, al-Farabi Kazakh National University

Abstract

In this paper, though various physical and chemical methods, the interaction of linear copolymers of AA-MA with PAA in aqueous solutions was studied. It was established that the binding polymers were made by hydrogen bonds and hydrophobic interactions. Also, it was concluded that with an increasing content of MA in the copolymer, the critical pH of complex formation range increases, however, at the same time the stability of interpolymer complex increases as well.

References

1. Mun G.A Hydrophilic polymers of vinyl ethers with linear and crosslinked structure and interpolymer complexes on their base // Avtoreferat of doctor degree dissertation.-Almaty.-2001.-Pp. 49. (in Russian).
2. Tsuchida; E.; Abe; K. Interactions between macromolecules in solution and intermacromolecular complexes // Adv. Polym. Sci.-1982.-V.45.-P.1-119.
3. Ikawa; T.; Abe; K.; Honda; K.; Tsuchida; E. Interpolymer complex between poly(ethylene oxide) and poly(carboxylic acid) // J. Polym. Sci.: Polym. Chem. Ed. 1975.-V.13;№ 7.-P.1505-1514.
4. Mun; G.A.; Khutoryanskiy; V.V.; Akhmetkalieva; G.T.; Shmakov; S.N.; Dubolazov; A.V.; Nurkeeva; Z.S.; Park; K. Interpolymer complexes of polyacrylic acid with poly2-hydroxyethylacrylate in aqueous solutions // Colloid Polym. Sci. – 2004. – V.283. – P.174-181
5. Nurkeeva; Z.S.; Mun; G.A.; Khutoryanskiy; V.V.; Bitekenova; A.B.; Dubolazov; A.V.; Esirkegenova; S.Zh. pH effects in the formation of interpolymer complexes between poly(N-vinylpyrrolidone) and polyacrylic acid in aqueous solutions // Eur. Phys. J.:Part E. – 2003. – V.10. – P.65-68.
6. Mun; G.A.; Nurkeeva; Z.S.; Khutoryanskiy; V.V. Complex formation between poly(vinyl ether) of ethylene glycol and poly(acrylic acid) in aqueous and organic solutions // Macromol. Chem. Phys.-1999.-V.200.-P.2136-2138.
Published
2013-06-20
How to Cite
ZHATKANBAYEVA, Zh. K. et al. Water soluble copolymers of acrylamide with methylacrylate in reactions of complex formation with polyacrylic acid. International Journal of Biology and Chemistry, [S.l.], v. 5, n. 1, p. 99-103, june 2013. ISSN 2409-370X. Available at: <https://ijbch.kaznu.kz/index.php/kaznu/article/view/88>. Date accessed: 20 sep. 2020.

Keywords

: interpolymer complex; linear copolymers; hydrogen bonds; hydrophobic interactions